FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000575859> ?p ?o ?g. }

• W2000575859 endingPage "288" @default.
• W2000575859 startingPage "284" @default.
• W2000575859 abstract "Reaction of 2-arylazo-4-methylphenol, (H2ap-R, where H2 indicates the two protons (the phenolic proton and one phenyl proton at the ortho position of the arylazo fragment) that undergo dissociation upon complexation) with [Os(PPh3)3Br2] in the presence of a base afford two types of organometallic complexes of osmium(III), viz. red [Os(PPh3)2(ap-R)Br] and brownish-green [Os(PPh3)(ap-R)(N–O)] [N–O is an iminosemiquinonate ligand generated from the 2-(arylazo)phenol via NN bond cleavage]. The structures of [Os(PPh3)2(ap-Cl)Br] and [Os(PPh3)(ap-Cl)(N–O)] have been determined by X-ray crystallography. In the [Os(PPh3)2(ap-R)Br] complexes, the ap-R ligand coordinates to osmium as a tridentate C,N,O donor ligand forming two five-membered chelate rings and the two PPh3 ligands are trans. In the [Os(PPh3)(ap-R)(N–O)] complexes, osmium is bound to one PPh3, one ap-R ligand coordinated as a tridentate C,N,O donor ligand and one iminosemiquinonate ligand. The [Os(PPh3)2(ap-R)Br] complexes are paramagnetic (low-spin d5, S = 1/2) and show anisotropic EPR spectra at 77 K. The [Os(PPh3)(ap-R)(N–O)] complexes are diamagnetic and show sharp 1H and 13C NMR signals. In acetonitrile solution all the complexes display intense charge-transfer transitions in the visible region. Cyclic voltammetry on these complexes in acetonitrile solution shows an osmium(III)–osmium(IV) oxidation positive to SCE and an osmium(II)–osmium(III) reduction negative to SCE. Two irreversible oxidations are also displayed by all the [Os(PPh3)(ap-R)(N–O)] complexes in the range 1.10–1.76 V vs. SCE." @default.
• W2000575859 created "2016-06-24" @default.
• W2000575859 creator A5009014980 @default.
• W2000575859 creator A5037290404 @default.
• W2000575859 creator A5088354240 @default.
• W2000575859 date "2001-01-01" @default.
• W2000575859 modified "2023-09-23" @default.
• W2000575859 title "Cyclometallation and NN bond cleavage of 2-(arylazo)phenols by osmium. Synthesis, structure and redox properties †" @default.
• W2000575859 cites W1559725132 @default.
• W2000575859 cites W1967301894 @default.
• W2000575859 cites W1967895364 @default.
• W2000575859 cites W1973402806 @default.
• W2000575859 cites W1981178032 @default.
• W2000575859 cites W1990969143 @default.
• W2000575859 cites W1994805605 @default.
• W2000575859 cites W1995287303 @default.
• W2000575859 cites W1997028450 @default.
• W2000575859 cites W1998061123 @default.
• W2000575859 cites W2001994116 @default.
• W2000575859 cites W2002315289 @default.
• W2000575859 cites W2002805284 @default.
• W2000575859 cites W2004880801 @default.
• W2000575859 cites W2011537140 @default.
• W2000575859 cites W2015089498 @default.
• W2000575859 cites W2016626713 @default.
• W2000575859 cites W2019322569 @default.
• W2000575859 cites W2020718635 @default.
• W2000575859 cites W2021917087 @default.
• W2000575859 cites W2034044092 @default.
• W2000575859 cites W2037262965 @default.
• W2000575859 cites W2042463049 @default.
• W2000575859 cites W2055604476 @default.
• W2000575859 cites W2057363758 @default.
• W2000575859 cites W2060094630 @default.
• W2000575859 cites W2068971512 @default.
• W2000575859 cites W2078126271 @default.
• W2000575859 cites W2081971388 @default.
• W2000575859 cites W2082495244 @default.
• W2000575859 cites W2107577608 @default.
• W2000575859 cites W2167567064 @default.
• W2000575859 cites W2313216737 @default.
• W2000575859 cites W2317433438 @default.
• W2000575859 cites W2949126522 @default.
• W2000575859 doi "https://doi.org/10.1039/b007486l" @default.
• W2000575859 hasPublicationYear "2001" @default.
• W2000575859 type Work @default.
• W2000575859 sameAs 2000575859 @default.
• W2000575859 citedByCount "39" @default.
• W2000575859 countsByYear W20005758592013 @default.
• W2000575859 countsByYear W20005758592014 @default.
• W2000575859 countsByYear W20005758592016 @default.
• W2000575859 countsByYear W20005758592020 @default.
• W2000575859 countsByYear W20005758592021 @default.
• W2000575859 crossrefType "journal-article" @default.
• W2000575859 hasAuthorship W2000575859A5009014980 @default.
• W2000575859 hasAuthorship W2000575859A5037290404 @default.
• W2000575859 hasAuthorship W2000575859A5088354240 @default.
• W2000575859 hasBestOaLocation W20005758592 @default.
• W2000575859 hasConcept C116569031 @default.
• W2000575859 hasConcept C155647269 @default.
• W2000575859 hasConcept C161790260 @default.
• W2000575859 hasConcept C170493617 @default.
• W2000575859 hasConcept C178790620 @default.
• W2000575859 hasConcept C179104552 @default.
• W2000575859 hasConcept C185592680 @default.
• W2000575859 hasConcept C2777463227 @default.
• W2000575859 hasConcept C3044715 @default.
• W2000575859 hasConcept C540285154 @default.
• W2000575859 hasConcept C55493867 @default.
• W2000575859 hasConcept C555196967 @default.
• W2000575859 hasConcept C55904794 @default.
• W2000575859 hasConcept C71240020 @default.
• W2000575859 hasConcept C8010536 @default.
• W2000575859 hasConceptScore W2000575859C116569031 @default.
• W2000575859 hasConceptScore W2000575859C155647269 @default.
• W2000575859 hasConceptScore W2000575859C161790260 @default.
• W2000575859 hasConceptScore W2000575859C170493617 @default.
• W2000575859 hasConceptScore W2000575859C178790620 @default.
• W2000575859 hasConceptScore W2000575859C179104552 @default.
• W2000575859 hasConceptScore W2000575859C185592680 @default.
• W2000575859 hasConceptScore W2000575859C2777463227 @default.
• W2000575859 hasConceptScore W2000575859C3044715 @default.
• W2000575859 hasConceptScore W2000575859C540285154 @default.
• W2000575859 hasConceptScore W2000575859C55493867 @default.
• W2000575859 hasConceptScore W2000575859C555196967 @default.
• W2000575859 hasConceptScore W2000575859C55904794 @default.
• W2000575859 hasConceptScore W2000575859C71240020 @default.
• W2000575859 hasConceptScore W2000575859C8010536 @default.
• W2000575859 hasIssue "3" @default.
• W2000575859 hasLocation W20005758591 @default.
• W2000575859 hasLocation W20005758592 @default.
• W2000575859 hasOpenAccess W2000575859 @default.
• W2000575859 hasPrimaryLocation W20005758591 @default.
• W2000575859 hasRelatedWork W1968841183 @default.
• W2000575859 hasRelatedWork W1995546051 @default.
• W2000575859 hasRelatedWork W2043560322 @default.
• W2000575859 hasRelatedWork W2044167576 @default.
• W2000575859 hasRelatedWork W2051981582 @default.

• next