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- W2000575959 abstract "Investigations of several different beta- and beta″-aluminas have found that cationic ordering phenomena play a major role in determining the properties of many of these systems. Low-temperature equilibrium states in the “single-ion” isomorphs of the beta″-aluminas are only attained by careful annealing treatments or by slow cooling the samples from the temperature of ion exchange. Rapidly cooled crystals contain non-equilibrium disordered arrangements that are responsible for the high ionic conductivity. In “mixed-ion” systems ordering between the different cations also inhibits the ionic conductivity. Beta″-aluminas containing two ions of different valence can form cationic arrangements involving substantial long-range correlations." @default.
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- W2000575959 date "1988-09-01" @default.
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- W2000575959 title "Studies of the equilibrium behaviour of crystalline fast-ionically conducting systems" @default.
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- W2000575959 doi "https://doi.org/10.1016/s0167-2738(88)80062-6" @default.
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