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- W2000576516 abstract "The limitations in the rates of polymerisation associated with the free radical process do not arise when styrene is polymerised by an anionic catalyst such as butyl lithium. However, if anionic catalysts are directly applied to pure styrene a thermal explosion follows. Some experiments are described in which sufficient low molecular weight polystyrene resin was added to the styrene to prevent boiling and the polymerisation was completed with butyl lithium. In spite of the dilution by low viscosity polymer, average molecular weights were obtained approaching those required for commercial polymer. Although purification criteria would have to be met there seems to be no fundamental obstacle to the development of small, high output polymerisation plants for making polystyrene." @default.
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- W2000576516 date "1975-05-01" @default.
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- W2000576516 title "Exploratory experiments on the fast anionic polymerisation of styrene" @default.
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- W2000576516 doi "https://doi.org/10.1002/pi.4980070308" @default.
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