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- W2000578040 abstract "In order to improve the physical properties of elastomers and to get more insight into the polymer dynamics close to filler interphases a carboxylated nitrile rubber (XNBR) was filled with up to 10 phr of layered silicate and investigated by dielectric and dynamic-mechanical analysis as well as by IR spectroscopy. Three relaxation processes have been detected beside the electrode polarization effect obtained in dielectric measurements. The relaxation process at low temper- atures can be assigned to the β-process due to the rotational motion of side groups. Its temperature dependence follows an Arrhenius-like behaviour and there is no significant change in the shape of this process with the incorporation of filler. The glass transition at medium temperature shows a Vogel-Fulcher-dependence but seems to be independent of filler as well. At higher temperatures a new relaxation process was detected which is probably due to the formation of zinc-carboxyl-clus- ters. In dielectric and dynamic-mechanical measurements this process increases with increasing loading of organoclay and is shifted to higher temperature." @default.
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- W2000578040 date "2008-01-01" @default.
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- W2000578040 title "Relaxation dynamics of carboxylated nitrile rubber filled with organomodified nanoclay" @default.
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- W2000578040 doi "https://doi.org/10.3144/expresspolymlett.2008.44" @default.
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