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- W2000578098 abstract "Organometallic complexes containing non-innocent ligands of the type Cp*Ir(tBAFPh)(1), where H2tBAFPh is 2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol, were found to activate H2 in a redox-switchable manner. The 16e- complex 1 was inert with respect to H2, CO, as well as conventional basic substrates until oxidation. Oxidation of 16-electron 1 with 1 equiv of Ag+ resulted in ligand-centered oxidation affording salts of [1]+, which were characterized by crystallographically, EPR, and elemental analyses. [1]+ was reduced to 1 in the presence of H2 and the sterically hindered base, 2,6-(tBu)2C5H3N, via a pathway that is first-order in both metal and dihydrogen. Compound [1]+ forms adducts with MeCN, which inhibits catalysis. The catalytic oxidation of H2 was established by electrochemical methods to be associated with the monocation." @default.
- W2000578098 created "2016-06-24" @default.
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- W2000578098 date "2007-12-29" @default.
- W2000578098 modified "2023-10-11" @default.
- W2000578098 title "Redox-Switched Oxidation of Dihydrogen Using a Non-Innocent Ligand" @default.
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- W2000578098 doi "https://doi.org/10.1021/ja076801k" @default.
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