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- W2000581611 abstract "Abstract The reaction of Co ( OH 2 ) 6 3 + with Co(dmgBF2)2(H2O)2 in 1.0 M HClO4/LiClO4 was found to be first-order in both reactants and the [H+] dependence of the second-order rate constant is given by k2obs = b/[H+], b at 25 °C is 9.23 ± 0.14 × 102 s−1. The [H+] dependence at lower temperatures shows some saturation effect that allowed an estimate of the hydrolysis constant for Co ( OH 2 ) 6 3 + as Ka = 9.5 × 10−3 M at 10 and 15 °C. Marcus theory and the known self-exchange rate constant for Co(OH2)5OH2+/+ were used to estimate an electron self-exchange rate constant of k22 = 1.7 × 10−4 M−1 s−1 for Co ( dmgBF 2 ) 2 ( H 2 O ) 2 + / 0 ." @default.
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- W2000581611 date "2005-09-01" @default.
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- W2000581611 title "Kinetic studies of the reduction of hexaaquacobalt(III) perchlorate by a cobaloxime, [Co(dmgBF2)2(H2O)2]" @default.
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- W2000581611 doi "https://doi.org/10.1016/j.ica.2005.06.064" @default.
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