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- W2000582679 abstract "WO3 microcrystals as small as 1000 Å were prepared by burning a tungsten wire in a gas mixture of Ar and O2. Raman spectra of the microcrystals were found to be much different from those of the bulk crystals. At room temperature, the microcrystals exhibit many peaks which are absent in the spectrum of the room-temperature phase of the bulk crystal (phase V). These peaks correlate fairly well with those of the low-temperature ferroelectric phase of the bulk crystal (phase VII). This implies that even at room temperature the low-temperature phase is mixed in the microcrystalline samples. When the samples are cooled down to 90 K, the Raman peaks corresponding to phase V disappear, those corresponding to phase VII become very strong and several new peaks appear. This result suggests that a new phase not reported so far appears at the low temperature." @default.
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- W2000582679 date "1990-08-01" @default.
- W2000582679 modified "2023-09-26" @default.
- W2000582679 title "Raman studies of phase transitions in gas-evaporated WO3 microcrystals" @default.
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- W2000582679 doi "https://doi.org/10.1016/0038-1098(90)90429-f" @default.
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