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- W2000582709 abstract "The title compound, [Hg(C(4)H(4)N(2)S)(C(4)H(3)N(2)S)](2)[HgBr(4)], consists of [Hg(pymt)(pymtH)](+) complex cations (pymtH is pyrimidine-2-thione) lying across twofold rotation axes in space group Fddd, with linearly coordinated mercury at an Hg-S distance of 2.357 (3) A, and [HgBr(4)](2-) anions lying at sites of 222 symmetry. The Hg atom is additionally coordinated by two N and two Br atoms, forming a 2+4 effective coordination sphere. The protonated ligand is connected via N-H.N hydrogen bonds to the neighbouring unprotonated ligand, thus forming infinite chains of cations." @default.
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- W2000582709 date "2004-01-10" @default.
- W2000582709 modified "2023-10-18" @default.
- W2000582709 title "A new complex of HgBr<sub>2</sub>and pyrimidine-2-thione: (pyrimidine-2-thionato-κ<i>S</i>)(pyrimidinium-2-thionato-κ<i>S</i>)mercury(II) tetrabromomercury(II)" @default.
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- W2000582709 doi "https://doi.org/10.1107/s0108270103028014" @default.
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