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- W2000583065 abstract "Using thiomorpholin-3-thione (ts) as ligand the complexes M(CO)5ts (where M = Cr, Mo, W), which are yellow, crystalline, non-electrolyte and diamagnetic, were obtained. Complexes of the types MX2ts2 and MX2ts (M = Zn, Cd, Hg; X = Cl, Br, I) were obtained as diamagnetic and non-electrolyte compounds. On the basis of i.r. and PMR spectra we suggest that the Cr, Mo and W-pentacarbonyl-derivatives have C4ν symmetry and are S-bonded through the thioketonic group, while all the IIB group derivatives seem to be N-bonded." @default.
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- W2000583065 date "1974-01-01" @default.
- W2000583065 modified "2023-09-26" @default.
- W2000583065 title "Group IIB metal and VIB metal-carbonyl thiomorpholin-3-thione derivatives" @default.
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- W2000583065 doi "https://doi.org/10.1016/0022-1902(74)80660-3" @default.
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