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- W2000584533 abstract "A permeable reactive barrier, consisting of both zero valent iron (ZVI) and a biodegradable organic carbon, was evaluated for the remediation of 1,1,2-trichloroethane (1,1,2-TCA) contaminated groundwater. During an 888 day laboratory column study, degradation rates initially stabilized with a degradation half-life of 4.4 ± 0.4 days. Based on the accumulation of vinyl chloride (VC) and limited production of 1,1-dichloroethene (1,1-DCE) and 1,2-dichloroethane (1,2-DCA), the dominant degradation pathway was likely abiotic dichloroelimination to form VC. Degradation of VC was not observed based on the accumulation of VC and limited ethene production.After a step reduction in the influent concentration of 1,1,2-TCA from 170 ± 20 mg L− 1 to 39 ± 11 mg L− 1, the degradation half-life decreased 5-fold to 0.83 ± 0.17 days. The isotopic enrichment factor of 1,1,2-TCA also changed after the step reduction from − 14.6 ± 0.7‰ to − 0.72 ± 0.12‰, suggesting a possible change in the degradation mechanism from abiotic reductive degradation to biodegradation. Microbiological data suggested a co-culture of Desulfitobacterium and Dehalococcoides was responsible for the biodegradation of 1,1,2-TCA to ethene." @default.
- W2000584533 created "2016-06-24" @default.
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- W2000584533 date "2010-11-01" @default.
- W2000584533 modified "2023-10-16" @default.
- W2000584533 title "A novel two-step treatment for the in situ bioremediation of chlorinated aliphatic hydrocarbons" @default.
- W2000584533 doi "https://doi.org/10.1016/j.jbiotec.2010.08.129" @default.
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