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- W2000584711 abstract "New chiral complexes of Pd(0) containing either the bis(phosphine) (6,6‘-dimethoxybiphenyl-2,2‘-diyl)bis(3,5-di-tert-butylphenylphosphine) (MeO-BIPHEP, 1) or the phosphine−sulfur chelate (2,3,4,6-tetra-O-acetyl-1-{(2-diphenylphosphino)benzyl)thio}-β-d-glucopyranose ((2-Ph2PC6H4CH2)−S−CHCH(OAc)CH(OAc)CH(OAc)CH(CH2OAc)O, 2) have been prepared, and the solid-state structure of one of these, Pd(benzoquinone)(2), has been determined. These Pd(0) complexes reveal interesting solution dynamics, as shown by 2-dimensional exchange spectroscopy. For the MeO-BIPHEP derivatives, one can obtain useful structural insights based on the observed restricted rotation around the aryl(3,5-di-tert-butylphenyl) P−C bonds." @default.
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- W2000584711 date "1997-07-01" @default.
- W2000584711 modified "2023-10-18" @default.
- W2000584711 title "New Chiral Complexes of Palladium(0) Containing P,S- and P,P-Bidentate Ligands" @default.
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- W2000584711 doi "https://doi.org/10.1021/om970185r" @default.
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