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- W2000586727 abstract "Reactions of CoH(N2)(PPh3)3 (I) and CoCH3(PPh3)3 (II) with various substituted olefins have been studied. Olefins having alkoxy, amide, and ester groups, such as isobutyl vinyl ether, acrylamide, methacrylamide and vinyl acetate, displaced all the triphenylphosphine ligands and gave complexes of the formula CoH(olefin)itn and Co(olefin)n (n = 2, 3); tetracyanoethylene and styrene displaced part of the triphenylphosphine ligands whereas acrylonitrile, methacrylonitrile and methyl methacrylate were polymerized by (I) and (II). The styrene complex obtained from (I) was characterized as Co(Styrene)[P(C6H4)Ph2](PPh3)2 where cobalt is bonded to an ortho carbon of one of the triphenylphosphine ligands." @default.
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- W2000586727 date "1973-10-01" @default.
- W2000586727 modified "2023-10-14" @default.
- W2000586727 title "Preparation of olefin-coordinated complexes by the reactions of cobalt-methyl and hydride complexes with substituted olefins" @default.
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- W2000586727 doi "https://doi.org/10.1016/s0022-328x(00)95053-8" @default.
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