FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000590802> ?p ?o ?g. }

• W2000590802 endingPage "2735" @default.
• W2000590802 startingPage "2728" @default.
• W2000590802 abstract "Abstract The interaction of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 (1) with azulene results in the formation of a complex, {[(o-C6F4Hg)3](azulene)} (2), containing one molecule of azulene per one macrocycle molecule. The complex represents a polydecker sandwich wherein the azulene units alternate with the molecules of the mercury anticrown. The reaction of 1 with 6-(N,N-dimethylamino)pentafulvene (DMAPF) also gives a 1:1 complex, {[(o-C6F4Hg)3](DMAPF)} (3), having a polydecker sandwich structure in the crystal. In complex 2, both the C5 and C7 rings of the azulene ligand are involved in the bonding to the Hg sites of 1. In complex 3, the C5 ring of the fulvene ligand together with its exocyclic carbon atom take part in the coordination to the mercury centres. In both adducts, the negatively charged five-membered ring of the azulene and, correspondingly, the fulvene moieties is arranged in the space between the central Hg3C6 rings of the adjacent macrocycles while the remaining portion of these moieties is disposed outside this space. The molecules of azulene and DMAPF in 2 and 3 are bonded to 1 through donation of their π-electrons on vacant orbitals of the Hg atoms. The synthesized 2 and 3 are the first examples of structurally characterized complexes of azulene and DMAPF with a non-transition metal compound." @default.
• W2000590802 created "2016-06-24" @default.
• W2000590802 creator A5019811362 @default.
• W2000590802 creator A5021029540 @default.
• W2000590802 creator A5038301705 @default.
• W2000590802 creator A5046932806 @default.
• W2000590802 creator A5059371612 @default.
• W2000590802 creator A5076101204 @default.
• W2000590802 creator A5082532445 @default.
• W2000590802 creator A5084937841 @default.
• W2000590802 date "2006-06-01" @default.
• W2000590802 modified "2023-09-26" @default.
• W2000590802 title "Coordination chemistry of anticrowns: Synthesis and X-ray crystal structure determination of the polydecker sandwich complexes of cyclic trimeric perfluoro-o-phenylenemercury with azulene and 6-(N,N-dimethylamino)pentafulvene" @default.
• W2000590802 cites W1491590045 @default.
• W2000590802 cites W1515322794 @default.
• W2000590802 cites W1549921146 @default.
• W2000590802 cites W1972583560 @default.
• W2000590802 cites W1977822926 @default.
• W2000590802 cites W1987698676 @default.
• W2000590802 cites W1989634843 @default.
• W2000590802 cites W1990516879 @default.
• W2000590802 cites W1994512928 @default.
• W2000590802 cites W2000739184 @default.
• W2000590802 cites W2001774535 @default.
• W2000590802 cites W2003357586 @default.
• W2000590802 cites W2010053045 @default.
• W2000590802 cites W2010236093 @default.
• W2000590802 cites W2015901023 @default.
• W2000590802 cites W2032576011 @default.
• W2000590802 cites W2037343769 @default.
• W2000590802 cites W2042213691 @default.
• W2000590802 cites W2044287989 @default.
• W2000590802 cites W2051442235 @default.
• W2000590802 cites W2053453103 @default.
• W2000590802 cites W2058862542 @default.
• W2000590802 cites W2059033805 @default.
• W2000590802 cites W2070217057 @default.
• W2000590802 cites W2071647214 @default.
• W2000590802 cites W2078552850 @default.
• W2000590802 cites W2088065073 @default.
• W2000590802 cites W2095213125 @default.
• W2000590802 cites W2096690326 @default.
• W2000590802 cites W2109285601 @default.
• W2000590802 cites W2132450679 @default.
• W2000590802 cites W2137401886 @default.
• W2000590802 cites W2144486442 @default.
• W2000590802 cites W2149087917 @default.
• W2000590802 cites W2152950225 @default.
• W2000590802 cites W2952024323 @default.
• W2000590802 doi "https://doi.org/10.1016/j.ica.2005.10.017" @default.
• W2000590802 hasPublicationYear "2006" @default.
• W2000590802 type Work @default.
• W2000590802 sameAs 2000590802 @default.
• W2000590802 citedByCount "17" @default.
• W2000590802 countsByYear W20005908022015 @default.
• W2000590802 countsByYear W20005908022016 @default.
• W2000590802 countsByYear W20005908022020 @default.
• W2000590802 countsByYear W20005908022021 @default.
• W2000590802 crossrefType "journal-article" @default.
• W2000590802 hasAuthorship W2000590802A5019811362 @default.
• W2000590802 hasAuthorship W2000590802A5021029540 @default.
• W2000590802 hasAuthorship W2000590802A5038301705 @default.
• W2000590802 hasAuthorship W2000590802A5046932806 @default.
• W2000590802 hasAuthorship W2000590802A5059371612 @default.
• W2000590802 hasAuthorship W2000590802A5076101204 @default.
• W2000590802 hasAuthorship W2000590802A5082532445 @default.
• W2000590802 hasAuthorship W2000590802A5084937841 @default.
• W2000590802 hasConcept C115624301 @default.
• W2000590802 hasConcept C120665830 @default.
• W2000590802 hasConcept C121332964 @default.
• W2000590802 hasConcept C178790620 @default.
• W2000590802 hasConcept C185592680 @default.
• W2000590802 hasConcept C188027245 @default.
• W2000590802 hasConcept C207114421 @default.
• W2000590802 hasConcept C2779328170 @default.
• W2000590802 hasConcept C2781203326 @default.
• W2000590802 hasConcept C50515024 @default.
• W2000590802 hasConcept C544153396 @default.
• W2000590802 hasConcept C62520636 @default.
• W2000590802 hasConcept C68913812 @default.
• W2000590802 hasConcept C71240020 @default.
• W2000590802 hasConcept C8010536 @default.
• W2000590802 hasConceptScore W2000590802C115624301 @default.
• W2000590802 hasConceptScore W2000590802C120665830 @default.
• W2000590802 hasConceptScore W2000590802C121332964 @default.
• W2000590802 hasConceptScore W2000590802C178790620 @default.
• W2000590802 hasConceptScore W2000590802C185592680 @default.
• W2000590802 hasConceptScore W2000590802C188027245 @default.
• W2000590802 hasConceptScore W2000590802C207114421 @default.
• W2000590802 hasConceptScore W2000590802C2779328170 @default.
• W2000590802 hasConceptScore W2000590802C2781203326 @default.
• W2000590802 hasConceptScore W2000590802C50515024 @default.
• W2000590802 hasConceptScore W2000590802C544153396 @default.
• W2000590802 hasConceptScore W2000590802C62520636 @default.
• W2000590802 hasConceptScore W2000590802C68913812 @default.
• W2000590802 hasConceptScore W2000590802C71240020 @default.
• W2000590802 hasConceptScore W2000590802C8010536 @default.
• W2000590802 hasIssue "9" @default.

• next