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- W2000593210 abstract "Trägerfreie PdRe-Katalysatoren wurden hinsichtlich ihrer Phasenzusammensetzung, Dispersität und katalytischen Aktivität mittels röntgenographischer Untersuchungen, Sorptionsmessungen (N2-Physisorption, CO-Chemisorption, H2-Sorption) bzw. katalytischer Messungen (Cyclohexandehydrierung, Benzolhydrierung) charakterisiert. Rhenium beeinflußt in starkem Ausmaß die Dispersität der Katalysatoren. Es gibt Hinweise dafür, daß zwischen der Volumen- und Oberflächenzusammensetzung der Legierungskristallite Unterschiede bestehen. Rhenium bewirkt außerdem eine synergetische Verbesserung der Proben bezüglich der katalytischen Aktivität. Es wird kurz auf Ähnlichkeiten zwischen PdRe- und PtRe-Katalysatoren eingegangen. Investigations on Metal Catalysts. XIV. Physico-chemical and Catalytical Properties of Palladium-Rhenium Catalysts Characterization of carrier-free PdRe catalysts with regard to their phase structure, dispersity and catalytical activity were performed by X-ray measurements, sorption methods (adsorption of N2, chemisorption of CO, sorption of H2), and catalytical investigations (dehydrogenation of cyclohexane, hydrogenation of benzene). The dispersity of the catalysts is influenced by thenium to a remarkable extent. There are references, that the composition of the bulk phase and the surface layer of the crystallites differs from each other. Also a synergistic effect in catalytical activity is caused by rhenium. The similarities between PdRe and PtRe catalysts are discussed briefly." @default.
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- W2000593210 date "1977-06-01" @default.
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- W2000593210 title "Untersuchungen an Metallkatalysatoren. XIV. Zu physikalisch-chemischen und katalytischen Eigenschaften von Palladium-Rhenium-Katalysatoren" @default.
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- W2000593210 doi "https://doi.org/10.1002/zaac.19774310121" @default.
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