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- W2000593221 abstract "endo-3-Diazotricyclo[3.2.1.02,4]oct-6-ene (endo-6) has already been prepared in solution. According to B3LYP/6-311+G(d,p) computations, the corresponding carbene endo-7 easily produces the highly strained neutral C8H8 compound 4 comprising a pyramidally tetracoordinated carbon which then rearranges to bridgehead alkene 15 through a cascade of rearrangements. Nonplanar diazocyclopropane structures are predicted for endo- and exo-6. Furthermore, their ring-opened isomers 27 are the first representatives of a new class of non-Kekulé compounds, the diazoallyls." @default.
- W2000593221 created "2016-06-24" @default.
- W2000593221 creator A5015168231 @default.
- W2000593221 creator A5079619663 @default.
- W2000593221 date "2006-08-04" @default.
- W2000593221 modified "2023-09-26" @default.
- W2000593221 title "Reactions of <i>e</i><i>ndo</i>-3-Diazotricyclo[3.2.1.0<sup>2,4</sup>]oct-6-ene, a Potential Precursor for the Generation of a Neutral C<sub>8</sub>H<sub>8</sub> Molecule with a Pyramidally Coordinated Carbon" @default.
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- W2000593221 doi "https://doi.org/10.1021/jo061082y" @default.
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