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- W2000594320 abstract "Abstract Nickel(II) halide complexes with the bidentate ligand 1,2-bis(diphenylphosphino)ethane (dpe) have been reinvestigated, with particular regard to their behaviour in solution. Conclusive evidence of the existence of low-spin five co-ordinate [Ni(dpe) 2 X] + species (X = Cl, Br, I), in equilibrium with cis -planar [Ni(dpe)X 2 ] species, is given on the basis of spectrophotometric and conductometric data. Calorimetric measurements suggest that the stability of five-co-ordinate [Ni(dpe) 2− Br] + is comparable to that of the previously reported [Co(dpe) 2 Br] + complex." @default.
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- W2000594320 date "1972-01-01" @default.
- W2000594320 modified "2023-10-02" @default.
- W2000594320 title "The solution behaviour of nickel(II) halide complexes of 1,2-bis(diphenylphosphino)ethane (dpe): The existence of five-co-ordinate [Ni(dpe)2X]+ species" @default.
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- W2000594320 doi "https://doi.org/10.1016/s0020-1693(00)91805-x" @default.
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