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- W2000595223 abstract "In this article, the solution-phase reaction of metal iodides with bphx yields two novel organic-inorganic hybrid clusteric halides: [(bphx)3(Pb3I8Br4)] and [(bphx)2(Cu4I8)] (bphx = 1, 6-bis(pyridinium)hexane dication), which are characterized by X-ray crystallography and IR spectroscopy. The title trinuclear compound 1 crystallizes in Orthorhombic, space group Pccn with a = 29.077(10)Å, b = 12.030(4)Å, c = 19.749(7)Å. Tetranuclear oligomer 2 crystallizes in Monoclinic, space group P2(1)/c with a = 10.1630(5)Å, b = 15.2477(7)Å, c = 15.3222(7)Å. Both compounds exhibit unusual supramolecular organization wherein bphx dications reside in the channels as an efficient template. The complex 2 gives a fluorescence center at 567 nm under excitation at 450 nm, which is considered to mainly arise from the [Cu4I8]4− unit." @default.
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- W2000595223 date "2011-07-01" @default.
- W2000595223 modified "2023-09-23" @default.
- W2000595223 title "Reactivity of Polyiodide Toward 1,6-Bis(pyridinium)hexane (bphx): Syntheses and Structures of Two Organic-Inorganic Hybrid Clusters [(bphx)3·(Pb3I8Br4)] and [(bphx)2·(Cu4I8)]" @default.
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- W2000595223 doi "https://doi.org/10.1080/15533174.2011.568447" @default.
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