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- W2000595805 abstract "Stimuli-responsive polymers and their application to biomaterials have been widely studied. On the other hand, as a novel biomimetic polymer, we have been studying the polymer with an autonomous self-oscillating function by utilizing oscillating chemical reactions. So far, we succeeded in developing a novel self-oscillating polymer and gels by utilizing the oscillating reaction, called the Belousov–Zhabotinsky (BZ) reaction, which is recognized as a chemical model for understanding several autonomous phenomena in biological systems. The self-oscillating polymer is composed of poly(N-isopropylacrylamide) (PNIPAAm) network in which the catalyst for the BZ reaction is covalently immobilized. Under the coexistence of the reactants, the polymer undergoes spontaneous cyclic soluble–insoluble changes or swelling–deswelling changes (in the case of gel) without any on–off switching of external stimuli. In this paper, our recent studies on the self-oscillating polymer gels and the design of functional material systems using the polymer are summarized." @default.
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- W2000595805 date "2009-12-01" @default.
- W2000595805 modified "2023-10-18" @default.
- W2000595805 title "Self-oscillating gel as novel biomimetic materials" @default.
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- W2000595805 doi "https://doi.org/10.1016/j.jconrel.2009.04.029" @default.
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