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- W2000597788 abstract "Die 5-Oxo-2,6-methano-2-benzazocine 2a und 2b werden mit NaBH4 und LiAlH4 in verschiedenen Lösungsmitteln reduziert, wobei die Stereoselektivität der Reduktion stark von der Stellung der Substituenten im Piperidonteil des Moleküls abhängig ist. Die Aufklärung der relativen Konfiguration der epimeren Alkohole erfolgt mit 1H-NMR- und 13C-NMR- spektroskopischen Methoden. Reductions of 3,11-Dipyridine Substituted 5-Oxo-2,6-methano-6-benz[c]azocine carboxylates The stereoselectivity of the reduction of 5-Oxo-2,6-methano-2-benzazocines with NaBH4 and LiALH4, respectively, in various solvents is mainly dependent on the position of the substituents in the piperidone part of the molecule. The relative configuration of the epimeric secondary alcohols is determined by means of 1H-NMR and 13C-NMR spectroscopic data." @default.
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- W2000597788 date "1989-01-01" @default.
- W2000597788 modified "2023-09-23" @default.
- W2000597788 title "Reduktionen 3,11-dipyridylsubstituierter 5-Oxo-2,6-methano-2-benzazocin-6-carbonsäureester" @default.
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- W2000597788 doi "https://doi.org/10.1002/ardp.19893220106" @default.
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