FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000597906> ?p ?o ?g. }

• W2000597906 endingPage "11983" @default.
• W2000597906 startingPage "11975" @default.
• W2000597906 abstract "We report novel transient infrared “tag and probe” investigations of the equilibrium kinetics and vibrational energy transfer between the free acid Et3SiOH and its 1:1 hydrogen-bonded complex with acetonitrile, Et3SiOH···N⋮CCH3, in dilute (0.1 mol/dm3 acid) CCl4 solutions at 293 K. Picosecond time-resolved infrared double-resonance spectroscopy measures the vibrational population of the OH-stretching mode (via v = 1 → 2 absorption) after IR excitation of either the free acid or the homogeneously broadened OH(v = 0 → 1) absorption of the complex. The free acid and 1:1 complex OH(v = 1) population lifetimes (T1) and equilibrium reaction rate constants affecting hydrogen-bond formation and dissociation are unambiguously determined for this system. Tagged free acid OH(v = 1) leads to complex formation with OH(v = 1) excitation, indicating OH(v = 1) population is maintained during collision and formation of hydrogen bonds. This is the only known example where OH(v = 1) vibrational population of a polyatomic reactant is prepared and that excitation is followed during a condensed-phase bimolecular reaction which leads to an excited hydrogen-bonded product." @default.
• W2000597906 created "2016-06-24" @default.
• W2000597906 creator A5032598541 @default.
• W2000597906 creator A5053699400 @default.
• W2000597906 date "1996-01-01" @default.
• W2000597906 modified "2023-10-03" @default.
• W2000597906 title "Conservation of Vibrational Excitation During Hydrogen-Bonding Reactions" @default.
• W2000597906 cites W1974761920 @default.
• W2000597906 cites W1976859651 @default.
• W2000597906 cites W1981418282 @default.
• W2000597906 cites W1982720337 @default.
• W2000597906 cites W1986914195 @default.
• W2000597906 cites W1987679902 @default.
• W2000597906 cites W1998491047 @default.
• W2000597906 cites W2006043456 @default.
• W2000597906 cites W2009371791 @default.
• W2000597906 cites W2011478408 @default.
• W2000597906 cites W2016671675 @default.
• W2000597906 cites W2016883201 @default.
• W2000597906 cites W2019080677 @default.
• W2000597906 cites W2035902610 @default.
• W2000597906 cites W2038380532 @default.
• W2000597906 cites W2042234096 @default.
• W2000597906 cites W2049866146 @default.
• W2000597906 cites W2051209845 @default.
• W2000597906 cites W2064556896 @default.
• W2000597906 cites W2065315120 @default.
• W2000597906 cites W2075250515 @default.
• W2000597906 cites W2077711650 @default.
• W2000597906 cites W2081286270 @default.
• W2000597906 cites W2082358041 @default.
• W2000597906 cites W2089946148 @default.
• W2000597906 cites W2097127157 @default.
• W2000597906 cites W2605005646 @default.
• W2000597906 cites W4300611374 @default.
• W2000597906 doi "https://doi.org/10.1021/jp960483m" @default.
• W2000597906 hasPublicationYear "1996" @default.
• W2000597906 type Work @default.
• W2000597906 sameAs 2000597906 @default.
• W2000597906 citedByCount "45" @default.
• W2000597906 countsByYear W20005979062012 @default.
• W2000597906 countsByYear W20005979062014 @default.
• W2000597906 countsByYear W20005979062015 @default.
• W2000597906 countsByYear W20005979062016 @default.
• W2000597906 countsByYear W20005979062018 @default.
• W2000597906 crossrefType "journal-article" @default.
• W2000597906 hasAuthorship W2000597906A5032598541 @default.
• W2000597906 hasAuthorship W2000597906A5053699400 @default.
• W2000597906 hasConcept C102931765 @default.
• W2000597906 hasConcept C112887158 @default.
• W2000597906 hasConcept C113196181 @default.
• W2000597906 hasConcept C119599485 @default.
• W2000597906 hasConcept C120665830 @default.
• W2000597906 hasConcept C121332964 @default.
• W2000597906 hasConcept C127413603 @default.
• W2000597906 hasConcept C144024400 @default.
• W2000597906 hasConcept C147789679 @default.
• W2000597906 hasConcept C149923435 @default.
• W2000597906 hasConcept C153642686 @default.
• W2000597906 hasConcept C178790620 @default.
• W2000597906 hasConcept C181500209 @default.
• W2000597906 hasConcept C184779094 @default.
• W2000597906 hasConcept C185592680 @default.
• W2000597906 hasConcept C24123453 @default.
• W2000597906 hasConcept C2908647359 @default.
• W2000597906 hasConcept C32909587 @default.
• W2000597906 hasConcept C512968161 @default.
• W2000597906 hasConcept C520434653 @default.
• W2000597906 hasConcept C55005982 @default.
• W2000597906 hasConcept C75473681 @default.
• W2000597906 hasConcept C83581075 @default.
• W2000597906 hasConceptScore W2000597906C102931765 @default.
• W2000597906 hasConceptScore W2000597906C112887158 @default.
• W2000597906 hasConceptScore W2000597906C113196181 @default.
• W2000597906 hasConceptScore W2000597906C119599485 @default.
• W2000597906 hasConceptScore W2000597906C120665830 @default.
• W2000597906 hasConceptScore W2000597906C121332964 @default.
• W2000597906 hasConceptScore W2000597906C127413603 @default.
• W2000597906 hasConceptScore W2000597906C144024400 @default.
• W2000597906 hasConceptScore W2000597906C147789679 @default.
• W2000597906 hasConceptScore W2000597906C149923435 @default.
• W2000597906 hasConceptScore W2000597906C153642686 @default.
• W2000597906 hasConceptScore W2000597906C178790620 @default.
• W2000597906 hasConceptScore W2000597906C181500209 @default.
• W2000597906 hasConceptScore W2000597906C184779094 @default.
• W2000597906 hasConceptScore W2000597906C185592680 @default.
• W2000597906 hasConceptScore W2000597906C24123453 @default.
• W2000597906 hasConceptScore W2000597906C2908647359 @default.
• W2000597906 hasConceptScore W2000597906C32909587 @default.
• W2000597906 hasConceptScore W2000597906C512968161 @default.
• W2000597906 hasConceptScore W2000597906C520434653 @default.
• W2000597906 hasConceptScore W2000597906C55005982 @default.
• W2000597906 hasConceptScore W2000597906C75473681 @default.
• W2000597906 hasConceptScore W2000597906C83581075 @default.
• W2000597906 hasIssue "29" @default.
• W2000597906 hasLocation W20005979061 @default.
• W2000597906 hasOpenAccess W2000597906 @default.
• W2000597906 hasPrimaryLocation W20005979061 @default.

• next