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• W2000602703 abstract "Hydrogen molecules in ZnO are identified by their local vibrational modes. In a Raman study, interstitial ${mathrm{H}}_{2}$, HD, and ${mathrm{D}}_{2}$ species were found to exhibit local vibrational modes at frequencies 4145, 3628, and $2985text{ }text{ }{mathrm{cm}}^{ensuremath{-}1}$, respectively. After thermal treatment of vapor phase grown ZnO samples in hydrogen atmosphere, most hydrogen forms shallow donors at the bond-centered site (${mathrm{H}}_{mathrm{BC}}$). Subsequently, ${mathrm{H}}_{mathrm{BC}}$ migrates through the crystal and forms electrically inactive ${mathrm{H}}_{2}$. These results imply that the ``hidden'' hydrogen in ZnO [G. A. Shi et al., Appl. Phys. Lett. 85, 5601 (2004)] occurs in the form of interstitial ${mathrm{H}}_{2}$." @default.
• W2000602703 created "2016-06-24" @default.
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• W2000602703 date "2009-05-08" @default.
• W2000602703 modified "2023-10-09" @default.
• W2000602703 title "Identification of Hydrogen Molecules in ZnO" @default.
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• W2000602703 doi "https://doi.org/10.1103/physrevlett.102.185502" @default.
• W2000602703 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19518886" @default.
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