Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000604996> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2000604996 endingPage "55" @default.
- W2000604996 startingPage "49" @default.
- W2000604996 abstract "Tributylstibine can mediate the olefination of carbonyl compounds with bromomalonic ester and with dibromomalonic ester. An initial halophilic attack of tributylstibine on the bromine of bromomalonic or dibromomalonic ester forming an ion pair of bromotributylstibonium cation and malonic (A) or bromomalonic ester carbanion (B), respectively, is proposed. These ion pairs react with carbonyl compounds to achieve subsequent olefination. Alternatively, 2 equiv of A collapse, with elimination of malonic ester, to form stiborane D, and the ion pair B reacts with another equivalent of tributylstibine to form stiborane D. This last undergoes a Wittig-type reaction with carbonyl compound to achieve olefination." @default.
- W2000604996 created "2016-06-24" @default.
- W2000604996 creator A5019103134 @default.
- W2000604996 creator A5023348560 @default.
- W2000604996 creator A5063253432 @default.
- W2000604996 creator A5084956584 @default.
- W2000604996 date "1990-01-01" @default.
- W2000604996 modified "2023-10-14" @default.
- W2000604996 title "Tributylstibine-mediated olefination of carbonyl compounds with bromomalonic ester and with dibromomalonic ester?A possible pathway through a stibonium ylide via halophilic initiation by tertiary stibines" @default.
- W2000604996 cites W1978066276 @default.
- W2000604996 cites W1985392194 @default.
- W2000604996 cites W1991237612 @default.
- W2000604996 cites W1992723080 @default.
- W2000604996 cites W2003785037 @default.
- W2000604996 cites W2016456504 @default.
- W2000604996 cites W2016831371 @default.
- W2000604996 cites W2017838364 @default.
- W2000604996 cites W2091981994 @default.
- W2000604996 cites W2149336222 @default.
- W2000604996 cites W2319298142 @default.
- W2000604996 cites W2325674370 @default.
- W2000604996 cites W2325715106 @default.
- W2000604996 doi "https://doi.org/10.1002/hc.520010108" @default.
- W2000604996 hasPublicationYear "1990" @default.
- W2000604996 type Work @default.
- W2000604996 sameAs 2000604996 @default.
- W2000604996 citedByCount "20" @default.
- W2000604996 countsByYear W20006049962017 @default.
- W2000604996 crossrefType "journal-article" @default.
- W2000604996 hasAuthorship W2000604996A5019103134 @default.
- W2000604996 hasAuthorship W2000604996A5023348560 @default.
- W2000604996 hasAuthorship W2000604996A5063253432 @default.
- W2000604996 hasAuthorship W2000604996A5084956584 @default.
- W2000604996 hasConcept C155647269 @default.
- W2000604996 hasConcept C178790620 @default.
- W2000604996 hasConcept C185592680 @default.
- W2000604996 hasConcept C24292678 @default.
- W2000604996 hasConcept C2776538354 @default.
- W2000604996 hasConcept C2779167645 @default.
- W2000604996 hasConcept C517835270 @default.
- W2000604996 hasConcept C523546767 @default.
- W2000604996 hasConcept C54355233 @default.
- W2000604996 hasConcept C80642116 @default.
- W2000604996 hasConcept C82894169 @default.
- W2000604996 hasConcept C86803240 @default.
- W2000604996 hasConceptScore W2000604996C155647269 @default.
- W2000604996 hasConceptScore W2000604996C178790620 @default.
- W2000604996 hasConceptScore W2000604996C185592680 @default.
- W2000604996 hasConceptScore W2000604996C24292678 @default.
- W2000604996 hasConceptScore W2000604996C2776538354 @default.
- W2000604996 hasConceptScore W2000604996C2779167645 @default.
- W2000604996 hasConceptScore W2000604996C517835270 @default.
- W2000604996 hasConceptScore W2000604996C523546767 @default.
- W2000604996 hasConceptScore W2000604996C54355233 @default.
- W2000604996 hasConceptScore W2000604996C80642116 @default.
- W2000604996 hasConceptScore W2000604996C82894169 @default.
- W2000604996 hasConceptScore W2000604996C86803240 @default.
- W2000604996 hasIssue "1" @default.
- W2000604996 hasLocation W20006049961 @default.
- W2000604996 hasOpenAccess W2000604996 @default.
- W2000604996 hasPrimaryLocation W20006049961 @default.
- W2000604996 hasRelatedWork W113798357 @default.
- W2000604996 hasRelatedWork W1965916428 @default.
- W2000604996 hasRelatedWork W1967241492 @default.
- W2000604996 hasRelatedWork W2024190341 @default.
- W2000604996 hasRelatedWork W2029624706 @default.
- W2000604996 hasRelatedWork W2316986873 @default.
- W2000604996 hasRelatedWork W2949087322 @default.
- W2000604996 hasRelatedWork W2950315075 @default.
- W2000604996 hasRelatedWork W2950624904 @default.
- W2000604996 hasRelatedWork W2523497260 @default.
- W2000604996 hasVolume "1" @default.
- W2000604996 isParatext "false" @default.
- W2000604996 isRetracted "false" @default.
- W2000604996 magId "2000604996" @default.
- W2000604996 workType "article" @default.