Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000605169> ?p ?o ?g. }
- W2000605169 endingPage "6588" @default.
- W2000605169 startingPage "6584" @default.
- W2000605169 abstract "It is an interesting phenomenon for natural organisms to have control over the shapes and sizes of inorganic nanocrystals and arrange them into ordered superstructures. This phenomenon attracts many attempts to mimic the biomineralization process to synthesize novel materials. In the present work, a new superstructure of hexagonal vaterite mesocrystals consisting of nanocrystals has been synthesized via a mesoscale transformation process by controlled release of carbon dioxide through slow decomposition of dimethyl carbonate in the presence of cetyltrimethyl ammonium bromide at room temperature. The superstructures are composed of hundreds of well-stacked vaterite flakes, which build spheres with an axis and two poles. We can find that mesocrystal plates at the poles are arranged with their surfaces parallel to the axis, whereas the plates at the equator of the spheres are arranged with their surface vertical to their axes. The flakes present the unstable (001) planes and show hexagonal shapes with a thick core and thin edges. The subunits of vaterite flakes consist of oriented aggregation of nanocrystals which are transformed from the amorphous phase. New evidence of the mesoscale transformation process has been observed in detail by measuring the structures of the products at different reaction stages, revealing that the product evolves from amorphous oblate particles to doughnutlike particles, which crystallize and delaminate into superstructures. The mineralization process is discussed with the cooperative reorganization of coupled inorganic and organic components relevant for models of matrix-mediated nucleation in biomineralization. This contribution will be helpful in understanding the aggregation-driven formation of complex and higher-order structured materials as well as the biomineralization mechanisms." @default.
- W2000605169 created "2016-06-24" @default.
- W2000605169 creator A5003612423 @default.
- W2000605169 creator A5003699233 @default.
- W2000605169 creator A5037374299 @default.
- W2000605169 creator A5038128096 @default.
- W2000605169 creator A5045126800 @default.
- W2000605169 creator A5052866578 @default.
- W2000605169 creator A5055183049 @default.
- W2000605169 creator A5061810022 @default.
- W2000605169 creator A5073746039 @default.
- W2000605169 date "2009-03-31" @default.
- W2000605169 modified "2023-10-11" @default.
- W2000605169 title "Superstructures and Mineralization of Laminated Vaterite Mesocrystals via Mesoscale Transformation and Self-Assembly" @default.
- W2000605169 cites W1484646597 @default.
- W2000605169 cites W1939452859 @default.
- W2000605169 cites W1975259769 @default.
- W2000605169 cites W1982100351 @default.
- W2000605169 cites W1982922019 @default.
- W2000605169 cites W1983706377 @default.
- W2000605169 cites W1989025984 @default.
- W2000605169 cites W1997020698 @default.
- W2000605169 cites W2006052585 @default.
- W2000605169 cites W2011266433 @default.
- W2000605169 cites W2013722136 @default.
- W2000605169 cites W2014830771 @default.
- W2000605169 cites W2023606692 @default.
- W2000605169 cites W2027762383 @default.
- W2000605169 cites W2037939607 @default.
- W2000605169 cites W2055826030 @default.
- W2000605169 cites W2060931826 @default.
- W2000605169 cites W2064126351 @default.
- W2000605169 cites W2068967745 @default.
- W2000605169 cites W2077732863 @default.
- W2000605169 cites W2079188969 @default.
- W2000605169 cites W2083841607 @default.
- W2000605169 cites W2085015653 @default.
- W2000605169 cites W2086904884 @default.
- W2000605169 cites W2090034151 @default.
- W2000605169 cites W2103836905 @default.
- W2000605169 cites W2115110079 @default.
- W2000605169 cites W2118226796 @default.
- W2000605169 cites W2120806719 @default.
- W2000605169 cites W2122311159 @default.
- W2000605169 cites W2128076815 @default.
- W2000605169 cites W2129690066 @default.
- W2000605169 cites W2150971711 @default.
- W2000605169 cites W2162475282 @default.
- W2000605169 cites W2163631907 @default.
- W2000605169 cites W2165985852 @default.
- W2000605169 cites W2168735797 @default.
- W2000605169 cites W4211113588 @default.
- W2000605169 doi "https://doi.org/10.1021/jp900475r" @default.
- W2000605169 hasPublicationYear "2009" @default.
- W2000605169 type Work @default.
- W2000605169 sameAs 2000605169 @default.
- W2000605169 citedByCount "26" @default.
- W2000605169 countsByYear W20006051692012 @default.
- W2000605169 countsByYear W20006051692013 @default.
- W2000605169 countsByYear W20006051692014 @default.
- W2000605169 countsByYear W20006051692016 @default.
- W2000605169 countsByYear W20006051692017 @default.
- W2000605169 countsByYear W20006051692018 @default.
- W2000605169 countsByYear W20006051692019 @default.
- W2000605169 countsByYear W20006051692021 @default.
- W2000605169 countsByYear W20006051692022 @default.
- W2000605169 countsByYear W20006051692023 @default.
- W2000605169 crossrefType "journal-article" @default.
- W2000605169 hasAuthorship W2000605169A5003612423 @default.
- W2000605169 hasAuthorship W2000605169A5003699233 @default.
- W2000605169 hasAuthorship W2000605169A5037374299 @default.
- W2000605169 hasAuthorship W2000605169A5038128096 @default.
- W2000605169 hasAuthorship W2000605169A5045126800 @default.
- W2000605169 hasAuthorship W2000605169A5052866578 @default.
- W2000605169 hasAuthorship W2000605169A5055183049 @default.
- W2000605169 hasAuthorship W2000605169A5061810022 @default.
- W2000605169 hasAuthorship W2000605169A5073746039 @default.
- W2000605169 hasConcept C127413603 @default.
- W2000605169 hasConcept C159467904 @default.
- W2000605169 hasConcept C159985019 @default.
- W2000605169 hasConcept C171250308 @default.
- W2000605169 hasConcept C175854130 @default.
- W2000605169 hasConcept C178790620 @default.
- W2000605169 hasConcept C183586093 @default.
- W2000605169 hasConcept C185592680 @default.
- W2000605169 hasConcept C192562407 @default.
- W2000605169 hasConcept C203036418 @default.
- W2000605169 hasConcept C2777163454 @default.
- W2000605169 hasConcept C2777739990 @default.
- W2000605169 hasConcept C2778039128 @default.
- W2000605169 hasConcept C2779465129 @default.
- W2000605169 hasConcept C2779866092 @default.
- W2000605169 hasConcept C42360764 @default.
- W2000605169 hasConcept C56052488 @default.
- W2000605169 hasConcept C58226133 @default.
- W2000605169 hasConcept C61048295 @default.
- W2000605169 hasConcept C8010536 @default.
- W2000605169 hasConceptScore W2000605169C127413603 @default.