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- W2000605535 abstract "In the solid solutions Pb(ZrxTi1−x)O3 it is stated that for x ≅ 0.55 there is a morphotropic phase change. Thermodynamically, it is expected that there will be a region of x, in which the two phases coexist and obey the leverage law. By X-ray diffraction, we found that the two phases coexist for x between 0.49 and 0.64. In this range the lattice parameters do not change, and the leverage law is obeyed. We conclude that an adequate explanation of the particular properties of the PZT solutions has to be found. Les solutions solides Pb(ZrxTi1−x)O3 sont décrites comme ayant un changement de phase morphotropique pour x ≅ 0.55. Mass des considérations thermodynamiques montrent que l'on doit s'attendre á observer un intervalle de valeurs de x pour lesquelles les deux phases coexistent et la loi du levier est verifiée. Par analyse des diagrames de diffraction des rayons X, on montre qu'il en est bien ainsi pour x compris entre 0.49 et 0.64. On en conclut qu'il n'existe pas encore d'explication satisfaisante des propriétés particuliéres de ces solutions solides." @default.
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- W2000605535 date "1974-09-01" @default.
- W2000605535 modified "2023-10-16" @default.
- W2000605535 title "X-ray study of the PZT solid solutions near the morphotropic phase transition" @default.
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- W2000605535 doi "https://doi.org/10.1016/0038-1098(74)90535-3" @default.
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