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- W2000606901 abstract "Abstract Formation mechanism of micro/nano-structures through competitive reactions in Mg/Cu super-laminate composites (SLCs) during initial hydrogenation was investigated experimentally. Three types of MgCu 2 structures, an open network, a sheathed network and a layer, were observed after initial hydrogenation of Mg/Cu SLCs under the conditions of 573 K, 86.4 ks in H 2 atmosphere of 3.3 MPa. Hydrogenation of Mg (1) and alloying Mg with Cu to form Mg 2 Cu (2) followed by hydrogenation of Mg 2 Cu (3) should be competitive. It is proposed that an open network of MgCu 2 can be formed when (1) occurs later than (3), a sheathed network when (1) occurs later than (2) and earlier than (3), and a layer when (1) occurs earlier than (2). However, the reaction of MgH 2 to Cu under H 2 atmosphere is not known in general. Therefore, in order to prove the existence and the generality of this reaction, pellets of MgH 2 and Cu powder were heated under the condition of 673 K, 86.4 ks in H 2 atmosphere of 8.0 MPa. The formation of a layer of MgCu 2 was confirmed by SEM observations, EDS analyses and XRD measurements." @default.
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- W2000606901 date "2015-10-01" @default.
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- W2000606901 title "Formation mechanism of micro/nano-structures through competitive reactions in Mg/Cu super-laminate composites during initial hydrogenation" @default.
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- W2000606901 doi "https://doi.org/10.1016/j.jallcom.2015.01.196" @default.
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