FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000607463> ?p ?o ?g. }

• W2000607463 endingPage "321" @default.
• W2000607463 startingPage "310" @default.
• W2000607463 abstract "Abstract Disulfide-linked manganese mesoporphyrin derivatives with spacer methylene-chain groups (Cn), (MnMP–Cn–S)2 [n=2, 6, 12] and one fluorinated mesoporphyrin derivative, (MnMPF4–C12–S)2 (Scheme 1) were synthesized and assembled on a gold electrode to study the nature of their electron transfer with respect to catalytic activity. The electron transfer of the mesoporphyrins from and to the self-assembled monolayers (SAMs) was measured in aqueous solution as well as in dimethyl sulfoxide (DMSO) using cyclic voltammetry and potential modulation reflectance, i.e., electroreflectance. Redox reaction of the mesoporphyrins on the electrode occurred between Mn(III) and Mn(II) occluded in the porphyrin ring. The rate constants of the electron transfer from and to the manganese mesoporphyrins on gold electrodes, estimated from the ER vs. modulation frequency relation, increased with the decreasing chain lengths but decreased due to fluorination of the porphyrin ring, which is in agreement with the rates for tetraphenyl porphyrins and its halogenated derivatives. Interestingly, the rate constants for the manganese mesoporphyrins in DMSO were greater than the rates for the tetraphenyl porphyrins and were enhanced by additional insertion of alkanethiols into the SAMs in aqueous solution." @default.
• W2000607463 created "2016-06-24" @default.
• W2000607463 creator A5000964009 @default.
• W2000607463 creator A5005652257 @default.
• W2000607463 creator A5006942700 @default.
• W2000607463 creator A5019421208 @default.
• W2000607463 creator A5028759956 @default.
• W2000607463 creator A5052490071 @default.
• W2000607463 creator A5055288189 @default.
• W2000607463 creator A5069708770 @default.
• W2000607463 creator A5080116853 @default.
• W2000607463 date "2005-03-01" @default.
• W2000607463 modified "2023-10-17" @default.
• W2000607463 title "Molecular assembly of manganese mesoporphyrin derivatives on a gold electrode and their electron transfer activity" @default.
• W2000607463 cites W1972060646 @default.
• W2000607463 cites W1973619705 @default.
• W2000607463 cites W1977398427 @default.
• W2000607463 cites W1978476140 @default.
• W2000607463 cites W1984550118 @default.
• W2000607463 cites W1988778563 @default.
• W2000607463 cites W1994631054 @default.
• W2000607463 cites W1996262798 @default.
• W2000607463 cites W2002024849 @default.
• W2000607463 cites W2008631597 @default.
• W2000607463 cites W2008768818 @default.
• W2000607463 cites W2012220720 @default.
• W2000607463 cites W2017670801 @default.
• W2000607463 cites W2026785149 @default.
• W2000607463 cites W2028152544 @default.
• W2000607463 cites W2029303812 @default.
• W2000607463 cites W2031904472 @default.
• W2000607463 cites W2032138379 @default.
• W2000607463 cites W2035573476 @default.
• W2000607463 cites W2045395419 @default.
• W2000607463 cites W2046000318 @default.
• W2000607463 cites W2048313475 @default.
• W2000607463 cites W2049098588 @default.
• W2000607463 cites W2054572177 @default.
• W2000607463 cites W2055503995 @default.
• W2000607463 cites W2055536502 @default.
• W2000607463 cites W2055929116 @default.
• W2000607463 cites W2063479915 @default.
• W2000607463 cites W2064608821 @default.
• W2000607463 cites W2065360689 @default.
• W2000607463 cites W2069553435 @default.
• W2000607463 cites W2070561115 @default.
• W2000607463 cites W2072110215 @default.
• W2000607463 cites W2072462309 @default.
• W2000607463 cites W2082770930 @default.
• W2000607463 cites W2092996809 @default.
• W2000607463 cites W2952419103 @default.
• W2000607463 cites W2986127853 @default.
• W2000607463 doi "https://doi.org/10.1016/j.tsf.2004.08.176" @default.
• W2000607463 hasPublicationYear "2005" @default.
• W2000607463 type Work @default.
• W2000607463 sameAs 2000607463 @default.
• W2000607463 citedByCount "7" @default.
• W2000607463 countsByYear W20006074632014 @default.
• W2000607463 crossrefType "journal-article" @default.
• W2000607463 hasAuthorship W2000607463A5000964009 @default.
• W2000607463 hasAuthorship W2000607463A5005652257 @default.
• W2000607463 hasAuthorship W2000607463A5006942700 @default.
• W2000607463 hasAuthorship W2000607463A5019421208 @default.
• W2000607463 hasAuthorship W2000607463A5028759956 @default.
• W2000607463 hasAuthorship W2000607463A5052490071 @default.
• W2000607463 hasAuthorship W2000607463A5055288189 @default.
• W2000607463 hasAuthorship W2000607463A5069708770 @default.
• W2000607463 hasAuthorship W2000607463A5080116853 @default.
• W2000607463 hasConcept C121332964 @default.
• W2000607463 hasConcept C123669783 @default.
• W2000607463 hasConcept C147120987 @default.
• W2000607463 hasConcept C147789679 @default.
• W2000607463 hasConcept C17525397 @default.
• W2000607463 hasConcept C178790620 @default.
• W2000607463 hasConcept C179104552 @default.
• W2000607463 hasConcept C185592680 @default.
• W2000607463 hasConcept C528890316 @default.
• W2000607463 hasConcept C62520636 @default.
• W2000607463 hasConcept C75473681 @default.
• W2000607463 hasConceptScore W2000607463C121332964 @default.
• W2000607463 hasConceptScore W2000607463C123669783 @default.
• W2000607463 hasConceptScore W2000607463C147120987 @default.
• W2000607463 hasConceptScore W2000607463C147789679 @default.
• W2000607463 hasConceptScore W2000607463C17525397 @default.
• W2000607463 hasConceptScore W2000607463C178790620 @default.
• W2000607463 hasConceptScore W2000607463C179104552 @default.
• W2000607463 hasConceptScore W2000607463C185592680 @default.
• W2000607463 hasConceptScore W2000607463C528890316 @default.
• W2000607463 hasConceptScore W2000607463C62520636 @default.
• W2000607463 hasConceptScore W2000607463C75473681 @default.
• W2000607463 hasFunder F4320320912 @default.
• W2000607463 hasFunder F4320321034 @default.
• W2000607463 hasIssue "1-2" @default.
• W2000607463 hasLocation W20006074631 @default.
• W2000607463 hasOpenAccess W2000607463 @default.
• W2000607463 hasPrimaryLocation W20006074631 @default.
• W2000607463 hasRelatedWork W1978289931 @default.
• W2000607463 hasRelatedWork W2047345785 @default.

• next