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- W2000608706 abstract "The molecular weight (MW) and the molecular weight distribution (MWD) of polyethylene (PE) prepared with various metallocene catalysts were investigated. The weight-average molecular weight (Mw) of PE prepared with dicyclopentadienyltitanium dichloride/aluminoxane (Cp2TiCl2/MAO) was about 4,0 · 105, while that of PE obtained with dicyclopentadienylzirconium dichloride/aluminoxane (Cp2ZrCl2/MAO) is about 1,0 · 105. PE of bimodal MWD was obtained with the mixed catalyst Cp2TiCl2/Cp2ZrCl2. Narrow MWD PE was obtained with the mixed catalyst Cp2ZrCl2/Et(ind)2ZrCl2, because each catalyst produced an Mw of 1,0 · 105. However, the change of temperature during the polymerization with the mixture Cp2ZrCl2/Et(ind)2ZrCl2 produced PE with a bimodal MWD and a value of the ratio of weight- to number-average molecular weights of Mw/Mn = 4." @default.
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- W2000608706 date "1995-08-01" @default.
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- W2000608706 title "Control of molecular weight and molecular weight distribution in ethylene polymerization with metallocene catalysts" @default.
- W2000608706 doi "https://doi.org/10.1002/macp.1995.021960816" @default.
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