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- W2000610310 abstract "The new mononuclear bis(oxamato) complex [n-Bu4N]2[Cu(obbo)] (1) (obbo=o-benzyl-bis(oxamato)) has been synthesized as a precursor for trinuclear oxamato-bridged transition metal complexes. Starting from 1 the homotrinuclear complexes [Cu3(obbo)(pmdta)2(NO3)](NO3)·CH2Cl2·H2O (2) and [Cu3(obbo)(tmeda)2(NO3)2(dmf)] (3) have been prepared, where pmdta = N,N,N′,N″,N″-pentamethyldiethylenetriamine, tmeda = N,N,N′,N′-tetramethylethylenediamine and dmf = dimethylformamide. The crystal structures of 1–3 were solved. The magnetic properties of 2 and 3 were studied by susceptibility measurements versus temperature. For the intramolecular J parameter values of −111 cm−1 (2) and −363 cm−1 (3) were obtained." @default.
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- W2000610310 date "2007-09-01" @default.
- W2000610310 modified "2023-10-18" @default.
- W2000610310 title "Synthesis, characterization, and magnetic properties of new homotrinuclear bis(oxamato) copper(II) complexes with an asymmetric central N,N′-bridge" @default.
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- W2000610310 doi "https://doi.org/10.1016/j.ica.2007.05.043" @default.
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