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- W2000613498 abstract "N-Acyliminium cyclization of 6-substituted (3R∗,6R∗,11aS∗)-3-arylmethyl-pyrazino[1,2-b]isoquinoline-1,4-diones gave with very good yields a novel tetrahydroisoquinoline pentacyclic core framework (29), while this reaction failed in all-cis-isomers to give instead conjugated enamines by deprotonation. Electronic and steric factors that govern the approach to both diastereomers from 6-substituted pyrazino[1,2-b]isoquinoline-1,4-diones have been studied." @default.
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- W2000613498 date "2009-03-01" @default.
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- W2000613498 title "Synthesis of a novel tetrahydroisoquinoline pentacyclic framework" @default.
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- W2000613498 doi "https://doi.org/10.1016/j.tet.2009.01.051" @default.
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