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- W2000613633 abstract "Abstract The electroreduction of camphorquinone, CQ, at a mercury electrode was studied by linear-sweep cyclic voltammetry in buffered aqueous solutions. A pre-peak system was observed at CQ concentrations above 5 × 10−4 M. The influence of pH, CQ concentration and scan rate on these peaks was studied. The experimental results can be justified only if the peaks are caused by the strong product adsorption at the electrode. At low scan rate values and high concentrations the behaviour can be explained if the adsorption is in equilibrium. In the rest of cases the process is controlled by the adsorption-desorption rate, even though some deviations from theoretical predictions are observed. Such deviations can be ascribed to the occurrence of side interactions between adsorbed molecules. The adsorption of CQ itself and the complexity of the reduction mechanism complicates the analysis of the adsorption—desorption pre-peak system." @default.
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- W2000613633 date "1993-10-01" @default.
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- W2000613633 title "Contribution to the elucidation of the redox behaviour of camphorquinone—II. Voltammetric study of the rate-controlled adsorption—desorption of the product of the electrode reaction on a mercury electrode" @default.
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- W2000613633 doi "https://doi.org/10.1016/0013-4686(93)80101-5" @default.
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