Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000615784> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2000615784 endingPage "1043" @default.
- W2000615784 startingPage "1036" @default.
- W2000615784 abstract "Solid solutions in the system, NH4Cl–MnCl2–H2O, exhibit properties characteristic of order-disorder in alloys. Disordered solid solutions are indistinguishable in structure from that of ammonium chloride. Order is revealed by superstructure formation. The familiar compositions A3B and AB appear as end-members of the ordered solid solution series. Crystal symmetry alteration from cubic to tetragonal results from ordering. Tetragonality is intimately related to the state of order. Though increase in ``solute'' content produces significant lattice distortion, superstructure unit cell volumes are constant. Despite their unusual properties, the ordered salt solid solutions exhibit a normal Vegard's law relationship. The salt system's features resemble those of a low temperature isotherm across Shockley's theoretical phase diagram for alloy order-disorder transformation and are regarded as experimental verification of Shockley's qualitative predictions. A concept of isothermal, compositional order-disorder is used in presenting the results. Demonstration of a two-phase region, wherein ordered and disordered solid solutions coexist in equilibrium, provides a basis for resolving the controversy over whether the phase rule governs order-disorder transformations. Identity of the order-disorder phenomenon in metal and salt systems was further shown by producing the disordered state of salt solutions from the ordered by thermal and cold-working methods. In both instances, order was spontaneously restored with aging at room temperature." @default.
- W2000615784 created "2016-06-24" @default.
- W2000615784 creator A5052568634 @default.
- W2000615784 date "1949-11-01" @default.
- W2000615784 modified "2023-09-25" @default.
- W2000615784 title "Isothermal Compositional Order-Disorder. I. Superstructure Solid Solutions in a Salt System" @default.
- W2000615784 cites W1492362589 @default.
- W2000615784 cites W1994319606 @default.
- W2000615784 cites W2031975877 @default.
- W2000615784 cites W2033460711 @default.
- W2000615784 cites W2054666327 @default.
- W2000615784 cites W2062194661 @default.
- W2000615784 cites W2092210396 @default.
- W2000615784 cites W2332168330 @default.
- W2000615784 doi "https://doi.org/10.1063/1.1747109" @default.
- W2000615784 hasPublicationYear "1949" @default.
- W2000615784 type Work @default.
- W2000615784 sameAs 2000615784 @default.
- W2000615784 citedByCount "9" @default.
- W2000615784 countsByYear W20006157842020 @default.
- W2000615784 crossrefType "journal-article" @default.
- W2000615784 hasAuthorship W2000615784A5052568634 @default.
- W2000615784 hasConcept C115624301 @default.
- W2000615784 hasConcept C121332964 @default.
- W2000615784 hasConcept C133347239 @default.
- W2000615784 hasConcept C138999460 @default.
- W2000615784 hasConcept C170751736 @default.
- W2000615784 hasConcept C178790620 @default.
- W2000615784 hasConcept C185592680 @default.
- W2000615784 hasConcept C191897082 @default.
- W2000615784 hasConcept C192562407 @default.
- W2000615784 hasConcept C195899389 @default.
- W2000615784 hasConcept C44280652 @default.
- W2000615784 hasConcept C8010536 @default.
- W2000615784 hasConcept C85906118 @default.
- W2000615784 hasConcept C89464430 @default.
- W2000615784 hasConcept C97355855 @default.
- W2000615784 hasConceptScore W2000615784C115624301 @default.
- W2000615784 hasConceptScore W2000615784C121332964 @default.
- W2000615784 hasConceptScore W2000615784C133347239 @default.
- W2000615784 hasConceptScore W2000615784C138999460 @default.
- W2000615784 hasConceptScore W2000615784C170751736 @default.
- W2000615784 hasConceptScore W2000615784C178790620 @default.
- W2000615784 hasConceptScore W2000615784C185592680 @default.
- W2000615784 hasConceptScore W2000615784C191897082 @default.
- W2000615784 hasConceptScore W2000615784C192562407 @default.
- W2000615784 hasConceptScore W2000615784C195899389 @default.
- W2000615784 hasConceptScore W2000615784C44280652 @default.
- W2000615784 hasConceptScore W2000615784C8010536 @default.
- W2000615784 hasConceptScore W2000615784C85906118 @default.
- W2000615784 hasConceptScore W2000615784C89464430 @default.
- W2000615784 hasConceptScore W2000615784C97355855 @default.
- W2000615784 hasIssue "11" @default.
- W2000615784 hasLocation W20006157841 @default.
- W2000615784 hasOpenAccess W2000615784 @default.
- W2000615784 hasPrimaryLocation W20006157841 @default.
- W2000615784 hasRelatedWork W1976428952 @default.
- W2000615784 hasRelatedWork W1989851337 @default.
- W2000615784 hasRelatedWork W2004710695 @default.
- W2000615784 hasRelatedWork W201313630 @default.
- W2000615784 hasRelatedWork W2014737864 @default.
- W2000615784 hasRelatedWork W2052901368 @default.
- W2000615784 hasRelatedWork W2060622188 @default.
- W2000615784 hasRelatedWork W2174897572 @default.
- W2000615784 hasRelatedWork W2282107112 @default.
- W2000615784 hasRelatedWork W2949595216 @default.
- W2000615784 hasVolume "17" @default.
- W2000615784 isParatext "false" @default.
- W2000615784 isRetracted "false" @default.
- W2000615784 magId "2000615784" @default.
- W2000615784 workType "article" @default.