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- W2000617327 abstract "Oxygen coordination of trivalent antimony is commonly discussed in terms of stereochemical activity of nonbonding electron pairs. In numerous solids, however, there are examples of coordinations which comprise three oxygen atoms in coplanar arrangements with the antimony atom. Arrangements of this kind cannot be explained satisfactorily by electron-pair repulsion. Die Sauerstoffkoordination des dreiwertigen Antimons wird allgemein auf die stereochemische Aktivität nichtbindender Elektronenpaare zurückgeführt. In zahlreichen Festkörpern finden sich jedoch Koordinationen, die drei Sauerstoffatome in koplanarer Anordnung mit dem Antimonatom enthalten. Solche Anordnungen können durch Elektronenpaarabstoßung nicht befriedigend erklärt werden." @default.
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- W2000617327 date "1985-11-01" @default.
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- W2000617327 title "Koplanaritätsbeziehungen in der Sauerstoffkoordination am dreiwertigen Antimon: neue Ausnahmen zu den Regeln der Elektronenpaarabstoßung" @default.
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- W2000617327 doi "https://doi.org/10.1016/0022-4596(85)90165-3" @default.
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