FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000618122> ?p ?o ?g. }

• W2000618122 endingPage "10638" @default.
• W2000618122 startingPage "10623" @default.
• W2000618122 abstract "Electronic structure calculations (DFT) suggest that ligand-stabilized three-membered gold(I) rings constituting the core structure in a series of cyclo-Au3LnH3-n (L = CH3, NH2, OH and Cl; n = 1, 2, 3) molecules exhibit aromaticity, which is primarily due to 6s and 5d cyclic electron delocalization over the triangular Au3 framework (s- and d-orbital aromaticity). The aromaticity of the novel triangular gold(I) isocycles was verified by a number of established criteria of aromaticity. In particular, the nucleus-independent chemical shift, NICS(0), the upfield changes in the chemical shifts for Li+, Ag+, and Tl+ cations over the Au3 ring plane, and their interaction with electrophiles (e.g., H+, Li+, Ag+, and Tl+) are indicative for the aromaticity of the three-membered gold(I) rings. Interestingly, unlike the respective substituted derivatives of cyclopropenium cation and the bora-cyclopropene carbacyclic analogues, the aromatic Au3 rings, although exhibit comparable diatropicity, react with electrophiles in a different way affording 1:1 and 2:1 sandwichlike complexes. The bonding in the three-membered gold(I) rings is characterized by a common ring-shaped electron density, more commonly seen in aromatic organic molecules and in “all-metal” aromatics, such as the cyclo-[Hg3]4- tetraanion. Moreover, the cation−π interactions in the 1:1 and 1:2 sandwichlike complexes formed upon reacting the Au3 rings with electrophiles, depending on the nature of the cation, are predicted to be predominantly electrostatic (Li+, Tl+) or covalent (H+, Ag+). The 1:2 complexes constitute a new class of sandwichlike complexes, which are expected to have novel properties and applications." @default.
• W2000618122 created "2016-06-24" @default.
• W2000618122 creator A5020722441 @default.
• W2000618122 creator A5051390224 @default.
• W2000618122 date "2005-07-12" @default.
• W2000618122 modified "2023-09-29" @default.
• W2000618122 title "Ligand-Stabilized Aromatic Three-Membered Gold Rings and Their Sandwichlike Complexes" @default.
• W2000618122 cites W105839754 @default.
• W2000618122 cites W1965272987 @default.
• W2000618122 cites W1970549136 @default.
• W2000618122 cites W1980609457 @default.
• W2000618122 cites W1981538261 @default.
• W2000618122 cites W1982407551 @default.
• W2000618122 cites W1982889116 @default.
• W2000618122 cites W1984094024 @default.
• W2000618122 cites W1984191478 @default.
• W2000618122 cites W1984731745 @default.
• W2000618122 cites W1992874177 @default.
• W2000618122 cites W1996712988 @default.
• W2000618122 cites W1999230610 @default.
• W2000618122 cites W2007713355 @default.
• W2000618122 cites W2011952416 @default.
• W2000618122 cites W2013213087 @default.
• W2000618122 cites W2014012031 @default.
• W2000618122 cites W2022190942 @default.
• W2000618122 cites W2023217497 @default.
• W2000618122 cites W2023271753 @default.
• W2000618122 cites W2026852240 @default.
• W2000618122 cites W2038767330 @default.
• W2000618122 cites W2044176936 @default.
• W2000618122 cites W2051879335 @default.
• W2000618122 cites W2054482550 @default.
• W2000618122 cites W2056655922 @default.
• W2000618122 cites W2057890351 @default.
• W2000618122 cites W2059279574 @default.
• W2000618122 cites W2065084130 @default.
• W2000618122 cites W2065680532 @default.
• W2000618122 cites W2070005238 @default.
• W2000618122 cites W2070467764 @default.
• W2000618122 cites W2073773983 @default.
• W2000618122 cites W2073815106 @default.
• W2000618122 cites W2083758181 @default.
• W2000618122 cites W2084165857 @default.
• W2000618122 cites W2089476172 @default.
• W2000618122 cites W2092443292 @default.
• W2000618122 cites W2102039279 @default.
• W2000618122 cites W2123605247 @default.
• W2000618122 cites W2133524519 @default.
• W2000618122 cites W2139608693 @default.
• W2000618122 cites W2141679702 @default.
• W2000618122 cites W2142511716 @default.
• W2000618122 cites W2143981217 @default.
• W2000618122 cites W2156115804 @default.
• W2000618122 cites W2167291867 @default.
• W2000618122 cites W2172918183 @default.
• W2000618122 cites W2282565472 @default.
• W2000618122 cites W28937944 @default.
• W2000618122 cites W2951866109 @default.
• W2000618122 cites W4231649355 @default.
• W2000618122 cites W4241057416 @default.
• W2000618122 doi "https://doi.org/10.1021/ja051415t" @default.
• W2000618122 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16045350" @default.
• W2000618122 hasPublicationYear "2005" @default.
• W2000618122 type Work @default.
• W2000618122 sameAs 2000618122 @default.
• W2000618122 citedByCount "41" @default.
• W2000618122 countsByYear W20006181222012 @default.
• W2000618122 countsByYear W20006181222013 @default.
• W2000618122 countsByYear W20006181222014 @default.
• W2000618122 countsByYear W20006181222016 @default.
• W2000618122 countsByYear W20006181222017 @default.
• W2000618122 countsByYear W20006181222019 @default.
• W2000618122 countsByYear W20006181222021 @default.
• W2000618122 countsByYear W20006181222022 @default.
• W2000618122 countsByYear W20006181222023 @default.
• W2000618122 crossrefType "journal-article" @default.
• W2000618122 hasAuthorship W2000618122A5020722441 @default.
• W2000618122 hasAuthorship W2000618122A5051390224 @default.
• W2000618122 hasConcept C116569031 @default.
• W2000618122 hasConcept C147597530 @default.
• W2000618122 hasConcept C161790260 @default.
• W2000618122 hasConcept C170493617 @default.
• W2000618122 hasConcept C178790620 @default.
• W2000618122 hasConcept C185592680 @default.
• W2000618122 hasConcept C192386470 @default.
• W2000618122 hasConcept C2780378348 @default.
• W2000618122 hasConcept C32909587 @default.
• W2000618122 hasConcept C50027330 @default.
• W2000618122 hasConcept C55493867 @default.
• W2000618122 hasConcept C70050531 @default.
• W2000618122 hasConcept C71240020 @default.
• W2000618122 hasConcept C8010536 @default.
• W2000618122 hasConceptScore W2000618122C116569031 @default.
• W2000618122 hasConceptScore W2000618122C147597530 @default.
• W2000618122 hasConceptScore W2000618122C161790260 @default.
• W2000618122 hasConceptScore W2000618122C170493617 @default.
• W2000618122 hasConceptScore W2000618122C178790620 @default.
• W2000618122 hasConceptScore W2000618122C185592680 @default.

• next