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- W2000621243 abstract "The total syntheses of vallesiachotamine 1 and isovallesiachotamine 2, indole alkaloids from dogbane plants, which are formed in vitro and in vivo from tryptamine and secologanin, were achieved by addition of silicon-stabilized anions to pyridinium salts and subsequent Pictet-Spengler reaction as the key reaction steps. Synthetic 1 and 2 were identical (except in their chiroptic properties) with authentic samples from plant cultures." @default.
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- W2000621243 date "1984-12-01" @default.
- W2000621243 modified "2023-10-12" @default.
- W2000621243 title "Total Synthesis of the Indole Alkaloid Vallesiachotamine" @default.
- W2000621243 doi "https://doi.org/10.1002/anie.198409841" @default.
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