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- W2000622662 abstract "La structure de A2M4O9 (A = Nb, Ta ; M = Mn, Fe, Co, Mg) a été étudiée aux rayons X. Elle dérive de la structure du corindon Al2O3—α par un ordre des cations A et M. Le groupe d'espace le plus probable est P 3̄ c 1. Les mesures magnétiques et la diffraction neutronique montrent la nature antiferromagnétique de Nb2Mn4O9 et de Nb2Co4O9. Les spins forment des chaînes selon les droites 13 23 z (spins +) et 23 13 z (spins −). The structure of A2M4O9 (A = Nb, Ta ; M = Mn, Fe, Co, Mg) has been studied by X-rays. It derives from the corundum type structure (α—Al2O9) by an ordering of the cations A and M. The most probable space group is P 3̄ c 1. Magnetic measurements and neutron diffraction show up the antiferromagnetic nature of Nb2Mn4O9 and Nb2Co4O9. The spins form chains along the lines 13 23 z (+ spins) and 23 13 z (− spins)." @default.
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- W2000622662 date "1961-12-01" @default.
- W2000622662 modified "2023-10-09" @default.
- W2000622662 title "Etude de niobates et tantalates de metaux de transition bivalents" @default.
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- W2000622662 doi "https://doi.org/10.1016/0022-3697(61)90103-2" @default.
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