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- W2000624772 abstract "A short total synthesis of the bacterial coenzyme methoxatin (1) (4,5-dihydro-4, 5-dioxo-1H-pyrrolo[2,3-f]quinoline-2,7,9-tricarboxylic acid) is described. The route involves the two step conversion of 4-acetamido-2-benzy1oxybenzaldehyde (5b) into methyl 6-acctamido-4-benzyloxyindole-2-carboxylate (7b) (74%), followed by regioselective annulation of the third ring (55%),and debenzylation and oxidation with benzoyl t-butyl nitroxide to give the tricyclic quinone triester (13) (methoxatin triester) (83%)." @default.
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- W2000624772 date "1986-01-01" @default.
- W2000624772 modified "2023-10-16" @default.
- W2000624772 title "Synthesis of the bacterial coenzyme methoxatin" @default.
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- W2000624772 doi "https://doi.org/10.1016/s0040-4020(01)87390-7" @default.
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