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- W2000636974 abstract "Mit Hilfe von 14C-Markierung wird gezeigt, das bei der Redox-Disproportionierung des 2,2-Di-hydroxyphenalen-1,3(2H)-dions (2) das C-2 als CO2 abgespalten wird. Die Bildung von Acenaphthenchinon (3) als Ringverengungsprodukt neben dem Redukton 4 ist als intramolekulare heterolytische Fragmentierung mit nachfolgender Oxidation interpretierbar.Mechanistic Investigations with the Aid of Isotopic Labeling, III1). — Redox-Disproportionation of 2,2-Dihydroxyphenalene-1,3(2H)-dioneIt is shown by means of 14C-labeling that redox-disproportionation of 2,2-dihydroxyphenalene 1,3(2H)-dione (2) leads to elimination of C-2 as CO2. Formation of the ring-contracted product acenaphthenequinone (3) and the reductone 4 is suggested to proceed as a heterolytic fragmentation reaction with subsequent oxidation." @default.
- W2000636974 created "2016-06-24" @default.
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- W2000636974 date "1978-10-24" @default.
- W2000636974 modified "2023-09-27" @default.
- W2000636974 title "Untersuchungen von Reaktionsmechanismen durch Isotopenmarkierung, III. Zur Redox-Disproportionierung von 2,2-Dihydroxyphenalen-1,3(2H)-dion" @default.
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- W2000636974 doi "https://doi.org/10.1002/jlac.197819781013" @default.
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