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- W2000642118 abstract "New ternary polyselenides Ba3TM2Se9 (TM = Nb, Ta) were synthesized through a solid-state reaction, and their structures were characterized using single-crystal X-ray diffraction. These compounds crystallized into a new structural type with a monoclinic space group P21/c. The structures were constructed from distorted, close-packed layers of ∞3[BaSe3]3.33– that incorporated TM atoms at octahedral sites and contained [(TM5+)2(Se2–)7(Se22–)] units. Diffuse reflectance spectra and electronic resistivity measurements indicated semiconducting properties and optical band gaps of 1.3 eV for Ba3Nb2Se9 and 1.6 eV for Ba3Ta2Se9. Raman spectra were used to investigate the interatomic interactions. Calculations of the electronic structure verified the semiconducting behavior and bonding interaction of short Se–Se contacts." @default.
- W2000642118 created "2016-06-24" @default.
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- W2000642118 date "2013-12-23" @default.
- W2000642118 modified "2023-09-28" @default.
- W2000642118 title "Ba<sub>3</sub>TM<sub>2</sub>Se<sub>9</sub> (TM = Nb, Ta): Synthesis and Characterization of New Polyselenides" @default.
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- W2000642118 doi "https://doi.org/10.1021/ic4013763" @default.
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