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- W2000642344 abstract "The 556 cm-1 Ag and 570 cm-1 B3g modes in the Raman spectrum of HoCrO3 show an anomalous blue-shift from a little above the Néel temperature to lower temperatures. Between TN and the ordering temperature of the Ho3+ spins the frequency shift is proportional to the Cr3+ spin correlation function. Above room temperature the 566 cm-1 mode frequency decreases to 566 cm-1 and then starts to increase to 570 cm-1 at 1000 K. The anomalous increase of scattering intensity of modes with energies higher than 300 cm-1, which appears to be proportional to the correlation function squared, is sensitive to the magnetic ordering. The sensitivity increases with the increase of mode energies. At about 50 K four additional modes appear." @default.
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- W2000642344 date "1986-03-01" @default.
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- W2000642344 title "Raman scattering and the antiferromagnetic phase transition in HoCrO3" @default.
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- W2000642344 doi "https://doi.org/10.1016/0304-8853(86)90127-7" @default.
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