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- W2000646046 abstract "Reaction of 3-O-benzyl-1,2-O-isopropylidene-α-xylo-pentodialdo-1,4-furanose with N,N-diethyl-2-(dimethylsulfuranilidene)acetamide gave stereoselectively an epoxyamide, which was regioselectively opened by NaN3 in dimethyl formamide to give the title compound, C21H30N4O6. X-ray crystallography confirmed the relative stereochemistry of the title compound and the absolute configuration was determined by the use of d-glucose as the starting material. There are two molecules in the asymmetric unit (Z′ = 2). The crystal structure consists of two types of chains of O—H⋯O hydrogen-bonded molecules running parallel to the b axis, with each molecule acting as a donor and acceptor of one hydrogen bond." @default.
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- W2000646046 date "2010-12-04" @default.
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- W2000646046 title "6-Azido-3-<i>O</i>-benzyl-6-deoxy-<i>N</i>,<i>N</i>-diethyl-1,2-<i>O</i>-isopropylidene-<scp>D</scp>-<i>glycero</i>-α-<scp>D</scp>-<i>gluco</i>-heptofuranuronamide" @default.
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- W2000646046 doi "https://doi.org/10.1107/s1600536810048944" @default.
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