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- W2000646472 abstract "The use of polar solvents such as nitromethane or 2-nitropropane leads to a significant improvement of the catalytic properties of a cationic copper-Lewis acid in the hetero Diels-Alder reaction of alkyl glyoxylates with dienes. The scope of a newly developed copper(II)-bisoxazoline catalyst for the hetero Diels-Alder reaction is demonstrated by the reaction of different dienes with alkyl glyoxylates in nitroalkane solvents with the formation of the hetero Diels-Alder adduct in high enantiomeric excess as the major product. The synthetic application of the reaction is exemplified by an improved synthesis of a highly interesting synthon for sesquiterpene lactones." @default.
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- W2000646472 title "Solvent effects in asymmetric hetero Diels-Alder and ene reactions" @default.
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- W2000646472 doi "https://doi.org/10.1016/0040-4020(96)00254-2" @default.
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