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• W2000648158 abstract "We propose a novel method to measure the parity-violating energy difference (PVED) between enantiomers using chiral ammonia-like molecules with tunnelling between L and D. The eigenstates of such molecules are Schrödinger's cat-type coherent superpositions of the L and D forms, but due to the PVED these “cat” states are slightly unequal superpositions of L and D, and therefore show a small electroweak optical rotation that is a direct measure of the PVED. We show that the rotational states of these “cat” molecules can be separated by applying an inhomogeneous electric field to a molecular beam. We calculate the optical rotations of the separated states, and show that they are measurable by state-of-the-art polarimeters for molecules with tunnelling times between 10−7 and 10−2 s." @default.
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• W2000648158 date "2004-10-01" @default.
• W2000648158 modified "2023-10-16" @default.
• W2000648158 title "A proposed experiment to measure the parity-violating energy difference between enantiomers from the optical rotation of chiral ammonia-like “cat” molecules" @default.
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• W2000648158 doi "https://doi.org/10.1016/j.chemphys.2004.06.017" @default.
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