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- W2000649874 abstract "The complex cis-[MoI4(dppe)]− is obtained in good yields from trans-[MoI4(THF)2]− and dppe (dppe = 1,2-bis(diphenylphosphino)ethane) or directly from the interaction of MoI3(THF)3, I− and dppe and has been isolated as the PPh4 and Na(THF)3 salts. The sodium salt has been characterized crystallographically; monoclinic P21/n, a = 12.790(2), b = 16.512(7), c = 23.117(4) Å, β = 103.65(1)°, V = 4744(1) Å3, Dcalc = 1.84 g cm−3, Z = 4, R = 0.039 for 4485 independent observed reflections (Fo2 ⩾ 3σ(Fo2). The structure features an octahedral coordination aroung both Na and Mo atoms in an overall face-sharing bioctahedral structure with the two metals being bridged by three iodide ligands. This is an unprecedented case of a structure containing an O3I3 coordination for Na ions and iodide ligands bridging sodium with a transition metal. The 1H NMR properties of the complex are also examined in comparison to those of the MoI3(dppe)(THF) precursor." @default.
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- W2000649874 title "Preparation of cis-[MoI4(Ph2PCH2CH2PPh2)]− and structure of (THF)3Na(μ-I)3MoI(Ph2PCH2CH2PPh2) with a new coordination environment around sodium" @default.
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- W2000649874 doi "https://doi.org/10.1016/0020-1693(94)04226-l" @default.
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