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• W2000652324 abstract "Vibrational state-to-state rate constants for CO deactivation in collisions with 14N2 are calculated in the temperature interval T=100–1000 K. The vibrational quantum number of CO and N2 runs in the interval 0–40 so that sufficiently wide samples of the VV and VT/R relaxation matrix for this important collisional system are obtained. The relative importance of one-quantum and multi-quantum transitions is also investigated. The theoretical results reproduce quite well the υ dependence of the transition probabilities experimentally determined by Hancock and Smith for the process: CO(υ - 1)+N2(υ′=1)→CO(υ)+ N2(υ′=0) - ΔE thus confirming that rate constants can be predicted by the semiclassical dynamical model used in this study within an accuracy of ≈ 30%." @default.
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• W2000652324 date "1984-09-01" @default.
• W2000652324 modified "2023-10-17" @default.
• W2000652324 title "Theoretical semiclassical investigation of the vibrational relaxation of CO colliding with 14N2" @default.
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• W2000652324 doi "https://doi.org/10.1016/0301-0104(84)85293-3" @default.
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