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- W2000653638 abstract "Abstract The crystal structure of Pb9O(OH)4A, zeolite 4A exchanged with Pb2+ at pH 6.0 and evacuated at 26°C, has been determined by single-crystal X-ray crystallography. Two separate (Pb2+, OH−, O2−) clusters were found. In each sodalite unit, a (Pb2+)3(O2−)(OH−)3 cluster, a distorted Pb4O4 cube with one Pb2+ missing, coordinates via its oxygens to four Pb2+ ions at 6-ring sites to give [Pb7O(OH)3]9+. In half of the large cavities, a [Pb2(OH)2]2+ cluster may have formed. The remaining Pb2+ ion is near the center of an 8-ring. The oxygen positions are somewhat uncertain, and the presence of hydrogen atoms is inferred." @default.
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- W2000653638 date "1993-02-01" @default.
- W2000653638 modified "2023-10-16" @default.
- W2000653638 title "Lead oxide hydroxide clusters in Pb9O(OH)4A, zeolite A exchanged with Pb2+ at Ph 6.0" @default.
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- W2000653638 doi "https://doi.org/10.1016/0144-2449(93)90067-d" @default.
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