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• W2000654551 abstract "Laser-ablated Ni atoms and electrons react with CO in excess argon during condensation to form the Ni(CO)1-4 complexes and Ni(CO)1-3- anions. Matrix infrared spectra of the neutral complexes with 12C16O, 13C16O, and 12C18O substitution are in agreement with earlier reports with thermal Ni atoms. In addition, new absorptions at 1847.0, 1801.7, and 1858.8 cm-1 exhibit isotopic spectra in excellent agreement with DFT calculations for the Ni(CO)1-3- anions. An experiment doped with the CCl4 electron-trapping molecule gave the same Ni(CO)1-4 spectrum without the corresponding anions, which strongly supports this identification of the molecular anions." @default.
• W2000654551 created "2016-06-24" @default.
• W2000654551 creator A5027565442 @default.
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• W2000654551 date "1998-10-17" @default.
• W2000654551 modified "2023-10-18" @default.
• W2000654551 title "Matrix Infrared Spectra and Density Functional Calculations of Ni(CO)<i>_x</i>^-, <i>x</i> = 1−3" @default.
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• W2000654551 doi "https://doi.org/10.1021/ja9820644" @default.
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