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- W2000655631 abstract "Two efficient approaches for the synthesis of isoindolin-1-one derivatives in phosphonium salt ionic liquids are described. The palladium-catalyzed carbonylation−hydroamination reaction of 1-halo-2-alkynylbenzene with amines afforded the substituted 3-methyleneisoindolin-1-ones in good yields and high selectivities in favor of the Z-isomers. The target molecules could also be synthesized by the Sonogashira coupling−carbonylation−hydroamination one-pot reaction of dihalides, alkynes, and amines. Both processes can be conducted under mild conditions and tolerate a wide array of functionalized substrates." @default.
- W2000655631 created "2016-06-24" @default.
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- W2000655631 date "2008-10-25" @default.
- W2000655631 modified "2023-10-06" @default.
- W2000655631 title "Syntheses of Substituted 3-Methyleneisoindolin-1-ones By a Palladium-Catalyzed Sonogashira Coupling−Carbonylation−Hydroamination Sequence in Phosphonium Salt-Based Ionic liquids" @default.
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- W2000655631 doi "https://doi.org/10.1021/ol8021403" @default.
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