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- W2000661503 abstract "Co-crystallization of a tri-ammonium cation with short and somewhat flexible ‘arms’, [N,N,N-tris[2-(dimethylamino)ethyl]-1,3,5-benzenetricarboxamide]3+, with a polyoxometalate trianion, PW12O403−, yielded an insoluble channeled or microporous structure. The polyoxometalate clusters are arranged in a layered and zig-zag fashion along the xy plane. Looking along the x-axis, channels of a dimension of ∼3.5×∼6.5 Å are observed. It was found that C–H⋯O bonds aided in determining the crystal packing by providing directionality to the anion–cation interaction. On the other hand the co-crystallization of a tetraammonium cation with an extended and rigid tetrahedral configuration, 1,3,5,7-tetrakis{4-[(E)-2(N-methylpyridinium-4-yl)vinyl]phenyl adamantane tetraiodide, with a polyoxometalate tetracation, SiW12O404−, yielded a lamellar structure with alternating layers with spacing of 16.6 Å of the inorganic–organic hybrid material." @default.
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- W2000661503 date "2003-08-01" @default.
- W2000661503 modified "2023-10-10" @default.
- W2000661503 title "Inorganic–organic hybrid materials based on keggin type polyoxometalates and organic polyammonium cations" @default.
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- W2000661503 doi "https://doi.org/10.1016/s0022-2860(03)00330-2" @default.
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