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- W2000664204 abstract "Transiodination occurs when reacting iodobenzenes with other halogeno-or with alkylbenzene derivatives in the presence of aluminium bromide at room temperature.Isomer equilibria among iodobenzenes resemble those for the corresponding bromides1. Di- and tri-substituted bromo- and iodo-benzenes show equilibrium patterns agreeing with those computed on the basis of addivitity, using patterns for monosubstituted halogenobenzenes. Results are discussed in terms of partial equilibrium factors1, believed to be mainly governed by electrostatic and steric interactions.Results of direct brominations (AlBr3 catalyst, no solvent) indicate that for halogeno- and alkylbenzenes the main difference between the isomer ratios observed and those at equilibrium consists in the large proportions of meta (or 1, 3, 5) isomer found in the latter case." @default.
- W2000664204 created "2016-06-24" @default.
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- W2000664204 date "2010-09-02" @default.
- W2000664204 modified "2023-09-25" @default.
- W2000664204 title "Equilibration of benzene derivatives. Part III: Mono- and poly-substituted iodo- and bromo-benzenes" @default.
- W2000664204 cites W1987894028 @default.
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- W2000664204 doi "https://doi.org/10.1002/recl.19670860202" @default.
- W2000664204 hasPublicationYear "2010" @default.
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