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- W2000665009 abstract "Five new mixed diimine 1,1‘-dithiolate or dithiocarbamate ligand complexes of the form [Rh(bpy)2(SS)][PF6]n, where bpy = 2,2‘-bipyridine and SS = various substituted dialkyldithiocarbamates or 1,1‘-dithiolates, were synthesized from cis-[Rh(bpy)2(OTf)2][OTf]. The triflate ligands are easily displaced by other ligands and allow these syntheses to proceed in high yields (80−90% overall) under relatively mild reaction conditions and to give high purity products. Electrochemistry shows irreversible two-electron reduction of Rh(III) to Rh(I) and a concomitant loss of one bipyridine ligand; this is followed by reversible one-electron reduction of the remaining 2,2‘-bipyridine ligand. The electronic characterizations of these complexes are consistent with significant delocalization of the sulfur electron density onto the empty metal d orbitals. The 1,1‘-dithiolate ligands induce larger red shifts in the absorption and emission spectra than the dithiocarbamates as the 1,1‘-dithiolates have a more extensive conjugation system." @default.
- W2000665009 created "2016-06-24" @default.
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- W2000665009 date "2005-10-29" @default.
- W2000665009 modified "2023-10-11" @default.
- W2000665009 title "Synthesis and Electronic Characterization of Bipyridine Dithiolate Rhodium(III) Complexes" @default.
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- W2000665009 doi "https://doi.org/10.1021/ic051171d" @default.
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